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山东大学学报(医学版) ›› 2009, Vol. 47 ›› Issue (7): 122-124.

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蔬菜表面残留磷酸酯类有机磷农药降解方法研究

季静,杨晓倩,郭冬梅,崔癉   

  1. 山东大学公共卫生学院卫生检验教研室, 济南 250012
  • 收稿日期:2008-12-25 发布日期:2009-07-16
  • 通讯作者: :崔癉,教授,主要从事微量元素与健康的研究。Email: cuixi@sdu.edu.cn
  • 作者简介:季静(1984- ),女,硕士研究生,主要从事微量元素与健康的研究。

Removing organophosphorus pesticide residues from vegetables by different methods

JI Jing, YANG Xiaoqian, GUO Dongmei, CUI Xi   

  1. Department of Chemical and Bacterial Detection, School of Public Health, Shandong University, Jinan 250012, China
  • Received:2008-12-25 Published:2009-07-16

摘要:

目的研究经存储、加工等不同处理方法对蔬菜中磷酸酯类有机磷农药残留的降解情况,比较家居生活中常用方法的去除效果。方法选取常用磷酸酯类有机磷农药制成蔬菜农药残留模型,采用不同方法处理,分别检测处理前后蔬菜表面农药残留量,计算去除率。结果蔬菜分别经放置24?h、光照、清水、盐水、碱水、沸水及有机磷农药降解酶处理后,韭菜中敌敌畏、氧化乐果、毒死蜱的平均去除率分别为95.5%~99.9%、22.5%~95.0%、51.7%~94.6%;豆角中敌敌畏、氧化乐果、毒死蜱的平均去除率分别为57.8%~99.9%、34.8%~83.1%、28.0%~73.6%。其中有机磷农药降解酶对敌敌畏去除效果最好,平均去除率为98.1%;沸水对氧化乐果、毒死蜱的去除效果最好,平均去除率分别为89.1%、82.3%。结论7种家居生活中常用方法均能不同程度的去除蔬菜表面磷酸酯类有机磷农药残留,要去除农药并尽可能保留营养素,有机磷农药降解酶的效果最佳。

关键词: 蔬菜;有机磷农药;残留;去除率

Abstract:

To evaluate the efficiency of different methods for removing organophosphorus pesticide residues from vegetables. MethodsVegetables were contaminated with pesticide, and then treated by different organophosphorus pesticide removal methods. Pesticide residue of vegetables was detected for calculating the removal rate. ResultAfter being treated by different organophosphorus pesticide removal methods, the average removal rates of dichlorvos, omethoate and chlorpyrifos were 95.5%99.9%, 22.5%95.0%, and 51.7%94.6% in Chinese chive, and were 57.8%99.9%, 34.8%83.1%, and 28.0%73.6% in legumes. Organophosphorus pesticidedegrading enzyme for removal of dichlorvos was the most effective, with an average removal rate of 98.1%. Boiling water was the best method to degrade omethoate and chlorpyrifos, with average removal rates of 89.1% and 82.3%, respectively. ConclusionMethods often being used in our daily life could remove organophosphorus pesticide residues of vegetables in different degrees. To remove pesticide and retain nutrients, organophosphorus pesticidedegrading enzyme is the best.

Key words: Vegetable; Organophosphorus pesticide; Residue; Removal rate

中图分类号: 

  • R155.5
[1] 马皎洁1,胡骁2,邵兵3,林肖惠4,于红霞1,李凤琴4. 超高效液相色谱-串联质谱法测定面粉、玉米及其制品中的伏马菌素研究[J]. 山东大学学报(医学版), 2012, 50(4): 115-120.
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